When blowing up multiple entities with a charged creeper (such as multiple wither skeletons, skeletons, zombies, and/or creepers the only head the drops is of the first mob spawned.
how to re-create:
spawn a creeper, wither skeleton, skeleton, and/or zombie in any order (make sure you know what order)
spawn a creeper near by, and strike it with lightning
activate the charged creeper with flitn and steel, and let it kill all the other mobs spawned
the result should be that the head dropped is that of the first mob you spawned.
EDIT: I tested this again with mobs at different locations instead of at the same location. the results are exactly the same.
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second attempt, but at multiple locations instead of just at a single location as in the first test.
Dupe of MC-63534