Mobs do not pathfind to cauldrons with water, even though it makes them not burn. They even sometimes get out of the cauldron, resulting in them burning.
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Can confirm
I can confirm for 20w46a.
Can confirm in 20w51a.
Can confirm in 21w03a.
Can confirm in 21w08b. Video attached.

Can confirm, but this seems totally normal. Cauldrons with water (though having extinguishing properties) don't act like normal water source blocks. Endermen don't die in them, and mobs can't pathfind to them. This feels like it's gonna be a "Won't Fix."