Steps to reproduce:
Enable RTX in game settings. (If not enabled already)
Join world.
Place structure block.
Open structure block UI and set to save mode.
Set length of selection along Z-axis to anything equal to or greater than 10 blocks
As of the latest stable version, Minecraft for Windows will immediately crash after this sequence of actions. I have verified that no single pack is at fault (tested with blank pack as well as VanillaRTX). If the Z-axis is already set greater than 10 blocks when opening the UI, the game will crash as well.
I cannot reproduce this. Could you attach a video of the issue?