Pressing Ctrl2 does nothing, really.
Look:
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The key combination for saving/loading hotbars was changed a few versions ago (as the old default caused people to accidently overwrite it). Check controls to get the new bindings; if I recall correctly it uses X and C.
I could, but I won't do so, because I don't see any bug here. Use the key that is specified in Options => Controls => Save Toolbar Activator
Did you change your key bindings to use
Ctrlfor saving toolbars?