I don't think it's intentional, but the armourer villager when zombie-fied is missing green pixels around their goggles (I'm assuming that they are supposed to be). Tested it in both 1.16.4 and 20w46a and recreated it, so i think it occurs often.
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This happened when I had normal armourer villagers, and zombified them. I just noticed that a few pixels around the goggles were still a villager skin colour rather than green like a zombie villager. Hope that makes sense
that brown part is part of the hat the villager wears, it's specifically in the armorer layer ((zombie) villagers use a base texture and add a layer for biome and profession on top)
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These pictures are both of zombie villagers, are you saying the problem is with zombified vs naturally spawned zombies.