In snapshot 4, unused GLFW functionality that would let you bind controls to a twenty-fifth function key if it existed was removed. The game now rejects such a control if found in the options menu. However it appears that the translation string still exists and is entirely unused, which can be verified in-game:
/tellraw @s {"translate":"key.keyboard.f25"}
Expected result would be for this string to be moved to deprecated, or removed entirely, as it is completely orphaned in its current state.
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Thank you for your report!
After consideration, the issue is being closed as Working as Intended.
Please note, that mechanics of the game may change between updates.
Things such as graphics, sounds, world creation, biomes, redstone, villagers, and animals may not work the same in current versions.
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