Currently you are unable to increase the player cap of PlayStation worlds from 5 without turning cheats on. I remember before the /setmaxplayers command worked with cheats off and it should resort to that way. My friends and I like playing with achievements on and it's really annoying that only 5 of us can play at once.
Thank you for your report!
We're actually already tracking this issue at MCPE-85009, so I will resolve and link this ticket as a duplicate.
If you would like to add a vote and any extra information to the main ticket it would be appreciated.
If you haven't already, you might like to make use of the search feature to see if the issue has already been mentioned.
Quick Links:
📓 Issue Guidelines – 💬 Community Support – 📧 Customer Support – ✍️ Feedback and Suggestions – 📖 Game Wiki