The bug
Unlike other commands such as /function, /structure fails to parse slashes correctly and requires identifiers that use them to be quoted.
How to reproduce
/function test/test
→ ✔ It correctly parses, but tells you the function was not found/structure load test/test ~ ~ ~
→ ❌ Syntax error
Also note that there are no command suggestions for structures even when files exist
Confirmed in 1.16.100.55.