Most blocks and some items exclusive to the education edition toggle cannot be obtained using /give (MCPE-110738) and /replaceitem, and cannot be placed using /fill or /setblock.
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The second image is me trying to search for a heat block "which is referred to as "chemical_heat". It does not show up in the command suggestions.
The second image is me trying to search for a heat block "which is referred to as "chemical_heat". It does not show up in the command suggestions.
Not being able to use /give for education edition items is already being tracked at MCPE-110738