Well, I tried it again with my daughter today as she was the first to notice it. It happened when I tried to replicate it that day, but now it isn't doing it anymore.
Working on aquiring a video of said issue.
I'm sure, I tested twice and it did it both times.
Using attached world files named "My Building World"
. Added corner block at -1 -19 -9 and named it "OakwoodManorV4"
3. Added corner block at -1 -19 77 and named it "OakwoodManorV4"
4. Added corner block at -1 -62 77 and named it "OakwoodManorV4"
5. Added corner block at 67 -19 77 and named it "OakwoodManorV4"
6. Added corner block at 67 -62 77 and named it "OakwoodManorV4"
7. Added corner block at 67 -19 -9 and named it "OakwoodManorV4"
8. Added corner block at 67 -62 -9 and named it "OakwoodManorV4"
9. Added structure block at -1 -62 -9 and named it "OakwoodManorV4"
10. Turned off "Include Entities" on structure block
11. Selected "Detect" on structure block
12. Structure block will not detect corner blocks