Place an End Crystal. Spawn/lure a creeper over to the area of the crystal. Make it explode (flint and steel or natural). If it blows up the End Crystal, it will sometimes drop gunpowder. This is not natural because the End Crystal is not killing the Creeper, the creeper is already dead at this point (because it blew up).
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No, I get that the Creeper can drop gunpowder. It shouldn't drop gunpowder after it explodes. I don't get why this is invalid.
Edit: Thank you for reopening it
michael
It can drop gunpowder, no guarantee.